3th WCSET-2014 at Nepal

Special Session at Ho Chi Minh City University of Technology, Vietnam:

Title:            Desulfurization of raw diesel fuel by metal-modified mesoporous silica
Authors:       Nguyen Thanh Luan, Le Thi Thuy Hang, Tran Tan Viet
Abstract:     Metal-modified mesoporous silica adsorbents (MCF-Ni, MCF-Ti) were prepared in order to selectively remove sulfur compounds from diesel fuel (470 ppmw of sulfur compounds) at room temperature. The properties of metal-modified mesoporous silica adsorbents such as BET surface area, pore volume, pore size, amount of metal were investigated. We showed that MCF-Ni and MCF-Ti can adsorb sulfur compounds from commercial fuels selectively at ambient temperature and pressure and the sulfur content was reduced more than 50% wt in a commercial diesel. In addition, the adsorption capacity and the regeneration ability toward sulfur compounds were investigated through batch experiments. The readsorption capacity for all adsorbents were close to their initial adsoption capacity when methyl isobutyl ketone (MIBK) was used for washing adsorbents and the regeneration ability of MCF-Ti adsorber was better than MCF-Ni.

Keywords:   Adsorption, Desulfurization, Diesel fuel, Mesoporous Silica, MCF
Pages:         718-723

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